![]() When they bond, sodium “gives” its valence electron to fluorine so they both can have eight valence electrons in their outer shells and be stable. Sodium has only one valence electron in its third shell while fluorine has seven valence electrons in its second shell (sodium doesn’t have a third shell). Antimony atom: Central Sb atom has Valence electron 05 Central Sb atom has Lone pair electrons 00 Central Sb atom has Bonding electrons 10 (five single bonds) Antimony atom has Formal charge (05 0 10/2) 0 So, SbF5 lewis structure has zero formal charge for the central antimony atom. Sodium fluoride (NaF) is a common example of a compound formed by an ionic bond. ![]() Ionic bonds tend to be stronger than covalent bonds. When one atom gains a valence electron while another atom loses a valence electron, that’s called an ionic bond. The second kind of bond is an ionic bond. To fix this, a hydrogen atom will share a valence electron from another hydrogen atom so they both find stability. Remember, the first shell can hold two electrons, so hydrogen is naturally unstable. A single hydrogen atom only has one outer shell and one valence electron. One example of a covalent bond is a hydrogen bond (or H₂). Covalent bonds happen when two atoms bond together by sharing valence electrons. The first kind is called a covalent bond. The elements of group 15 (column) VA of the periodic table all have electron configurations of s2 p3, giving them five valence electrons. So, what do atoms do if their outermost shell isn’t completely filled with valence electrons? They bond with other unstable atoms! There are two basic kinds of bonds: This is why elements like neon and argon don’t really react with other elements (because their outermost shell is naturally full with eight valence electrons). When the outer shell around an atom is filled with valence electrons, the atom is stable and doesn’t need to interact with other atoms to find stability. (Different elements have different numbers of shells, each shell can hold only a fixed number of electrons, and there’s a formulaic way to determine that number).Ītoms-perhaps not unlike people?!-have one primary goal: to become stable. The second shell can hold up to eight electrons, the third up to 18. The shell closest to the nucleus can hold two electrons. Electrons surround the nucleus in shells. The nucleus (or the center of an atom) consists of neutrons and protons. Some fundamentals: atoms are made up of neutrons, protons, and electrons. Electron configuration of Antimony is Kr 4d10 5s2 5p3. Electron Configuration and Oxidation States of Antimony. Lewis (an American chemist and professor at University of California, Berkeley) significantly contributed to our understanding of valence electrons. Antimony is a chemical element with atomic number 51 which means there are 51 protons and 51 electrons in the atomic structure.The chemical symbol for Antimony is Sb. Valence Electrons in Antimony Antimony (Sb) has an atomic number of 51. Phosphorus has the +1 oxidation state in hypophosphorous acid and the +4 oxidation state in hypophosphoric acid. Atoms may be teeny-tiny, but they have a lot going on beneath the surface. A corresponding compound for antimony is Sb 2 (C 6 H 5) 4, where the antimony's oxidation state is +II.
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![]() The combination of my technology background and my business and marketing acumen was in high demand as the Internet rapidly brought change to the industry.Īfter reading Naked Conversations, I was motivated to better brand and control the content on the site. Over time, I found out that more and more of the group were coming to me for technology advice. I belonged to a Marketing Book club in Indianapolis that quickly grew out of control. I was all over the place and mostly wrote for myself – without much of an audience. I began blogging on Blogger and waxed poetic about everything from politics to Internet tools. Years later I sold the domain to a company that helped folks quit smoking, one of my first big contracts. My first site was a site called Helping Hand that curated the best sites from around the web to help people with their computers and with navigating resources on the Internet. I started my work on the web more than two decades ago. Our clients that may have an emergency can always call us.ĭisclosure: I’m using my referral link in the post in the hopes that a ton of you install and pay for the service and I can get it for free! □ I’d rather pause receiving emails until the following business day. It’s not that we don’t want to be responsive, but we’re often training our clients that they can practically connect with us any time of the day or night… not a great practice since we’re not a support department. Too many times we receive late night emails from clients with requests that we jump on. I’m absolutely thrilled that MailButler has the Inbox Pause feature under development. Giphy – With MailButler you have direct access to a trazillion animated images to better express yourself.Quote – Quickly share a quote from an email message in other applications or services.Inbox Pause – Have a break, have MailButler: Automatically disable certain email accounts based on your working hours.Tasks – Mark your emails as to-do items to never forget about important tasks again.One of the features I love is that it maintains my last setting – so I have Next Business Day at 8:00 AM. This is great because I don’t really care for people seeing that I’m responding to their email at 2:48 AM, heh. Here’s a shot of how simple the MailButler scheduling works. 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Tracking – Let you know if the recipient has actually opened your email.Snooze – By snoozing an email you will temporarily make it disappear out of your Inbox.It’s so good that Apple should really just snap this company up and add these features by default. Unlike many third party platforms that inspect or take over your inbox, MailButler is an add-on that integrates seamlessly with Apple Mail. And I know that for every few hundred emails, there’s always a nugget of opportunity in a couple that I should be on top of.Ībout a week ago, Thaddeus Rex, a brand expert that works with us on clients who may or may not have witnessed me openly weeping in front of my inbox, let me know about MailButler. I want to manage the wave of requests better. I’ve deployed a ton of tools to assist and I’ve always been disappointed, tossing them all and returning to Apple Mail whose flags, filters, and VIP lists are fingers that I use to plug the dam. My inbox is out of control and inbox zero is as realistic to me as a pink dinosaur. And that’s not including subscriptions to newsletters that I love. I send about 100 emails and receive about 200 emails every day. I have 1,021 unread emails and my non-response is running over into direct messages via social media, phone calls, and text messages. As I write this, I’m currently in mail hell. ![]() The cookie is set by the GDPR Cookie Consent plugin and is used to store whether or not user has consented to the use of cookies. S&P500 Average DrawDown Stats since 1900 in numbers The current drawdown hasnt ended yet. S&P500 Average DrawDown Stats since 1900 We can deduct from the chart above that usually the bigger the drawdown the longer it takes to recover from it. ![]() The cookie is used to store the user consent for the cookies in the category "Performance". The chart below give an average stats of all draw downs since 1900. This cookie is set by GDPR Cookie Consent plugin. The cookie is used to store the user consent for the cookies in the category "Other. The cookies is used to store the user consent for the cookies in the category "Necessary". The cookie is set by GDPR cookie consent to record the user consent for the cookies in the category "Functional". The cookie is used to store the user consent for the cookies in the category "Analytics". Investors and financial analysts consider it when building portfolios because the maximum drawdown hints about future risk. These cookies ensure basic functionalities and security features of the website, anonymously. The maximum drawdown is a financial indicator that shows how much the value of an investment has lost from its last peak or maximum value. Simply go to and look for the chart banner, fill out the information required and we will send you this dazzling color tool.Necessary cookies are absolutely essential for the website to function properly. ![]() The higher resolution printing process we’re using to create this chart will make the blue, green and orange tones much more vibrant, offering the truest printed color interpretation available. Starting this February we are offering this rolled poster to all our customers for $9.95 (plus shipping and handling). Just looking at these imperfect representations on your computer monitor still gives an incredible reference as to how the very subtle differences in color, tints or glazes makes all the difference as to how these various pigments react and move in color space. Embedded into this article are some of these drawdowns. You can see Sarah’s article on our current Web site at here. It didn’t take long for the idea to take hold that these color samples even in printed form would be incredibly valuable for all our customers … so was born the new Drawdown Color Chart Poster. ![]() Word got out to the rest of the artists in the company that we had all these drawdowns and soon, requests began to pour into the lab for these color samples. When we counted the colors and the number of drawdowns, (close to 1,000 for one complete set) it was clearly not something we could do by hand, but we would certainly consider putting all the data into a form that could be used by all the team members. This quickly resolved into requests to have all our colors analyzed in multiple tint and glaze let downs. All the members, being incredible color fanatics, wanted a full set of the dried color samples for their own work. Drawdown chart Drawdown chart The chart displays loosing periods of a program and selected benchmarks. When Sarah Sands wrote “The Subtleties of Color” in our last issue of Just Paint (#21) we assembled the entire Tech Support Services team to review the enormous number of exquisite drawdowns that had been created to then generate all the spectral data. If you only want to export a single query to a CSV file, use. mode dot command in conjunction with the. Create and manage SQL Server Merge Replication subscriptionsįor support, full source code, and standalone versions for 4.0 and 3.5 (for VS Express and non-VS users) and feedback, go to: - the source code also includes a scripting API and command line versions of many of the features in the Toolbox.When using the SQLite command line shell, you can export your query results to a CSV file by using the.Extensive support for Sync Framework 2.1, including Provisioning, Deprovisioning, Code Generation, Local Database Cache Code Generation and Explorer tree integration.Upgrade version 3.1/3.5 files to version 4.0 in a single step.About box with detailed SQL Server Compact engine version information.Maintain databases: Set password, Verify, Shrink, Compact, Repair (SQLCE), Vaccum, Reindex (SQLite).Data types node with documentation tooltips lists the 18 available data types in SQL Server Compact.Generate database documentation in HTML or XML formats, courtesy of DB>doc for Microsoft SQL Server.Add object descriptions to databases, tables and columns- Generate detailed DGML files for visualizing table columns and relationships (requires VS Community or Pro to view).Full integration with Entity Framework 6.x Tools in VS 2012 and later to enable "EF Designer from Database", "Code First from database" and "Generate Database from Model" workflows for SQL Server Compact 4.0 and SQLite.Generate SQLite based sqlite-net code for use in WinRT, Windows Phone and Universal apps.Generate desktop LINQ to SQL classes for SQL Server Compact 3.5 and 4.0 databases.vb) (for SQLCE 3.5 only) in the current project, with optional ConnectionStringBuilder class Generate Windows Phone LINQ to SQL DataContext classes (.cs or.View table data as a report, with options to page through data, print and export as Excel/Word/PDF.Edit table data in a grid, with column sorting, clever column sizing, image import/export, quick search and free form query.Explore query results with filtering, sorting and grouping.Display graphical estimated and actual execution plan.Basic, free form query execution in editor with syntax coloring, support for large files, and built-in search with result highlighting.Build CREATE TABLE scripts, and Index/Column and Foreign Key scripts from the UI.Create database table data diff scripts, compare with a SQL Server Compact or even a SQL Server database.Create database schema diff scripts, compare with a SQL Server Compact or even a SQL Server database.Migrate from SQL Server or SQLite to SQL Server Compact, either via script or in a single step.Migrate from SQL Server Compact or SQLite to SQL Server, SQL Azure and SQLite via script.Migrate a SQL Server Compact or SQLite database directly to SQL Server (LocalDB/Express).Import to SQL Server Compact or SQLite from a SQL Server database or a CSV file. ![]() Script entire schema and/or all data from SQL Server Compact, SQLite and SQL Server databases, and choose tables to script - with high fidelity.Remove invalid Data Sources from the Toolbox (and Server Explorer)Ĭopy the database file for example to your project or any other folder Scan current Solution for SQL Compact and SQLite files, and add these to the Toolboxĭisplays object properties in Properties windowĮxplore all database objects: Tables, Columns, Indexes, Keys, Views, Triggers, Statistics, Merge Subscriptions, Sync Scopes Lists all SQL Server, SQL Server Compact and SQLite Data Sources defined in Server Explorer The SQL Server Compact & SQLite Toolbox adds several features to help your SQL Server Compact and SQLite development efforts:Ĭonnect to SQL Server Compact 4.0, 3.5, SQL Server and SQLite database files in Visual Studio 2017 and later. If you need a Visual Studio 2010 version of this extension, please contact me via Github/email Release notes - 4.5 and 4.4 features - 4.3 features - 4.2 features - 4.1 features - 4.0 features Provide implementation guidance based on best practices to the organization throughout the workload lifecycle. The exam also validates a candidate’s ability to complete the following tasks: Design a solution by using appropriate AWS services and by following architectural principles based on requirements. AWS Certification helps you build credibility and confidence by validating your cloud skills with industry-recognized credentials. The exam validates a candidate’s ability to design secure and robust solutions by using AWS technologies. The AWS Certified Solutions Architect – Associate exam is intended for individuals who perform in a solutions architect role. Steps To AWS Certified Solutions Architect - Associate Certification Step 1:Review the skills and knowledge required to certify. ![]() ![]() Earn the AWS Certified Cloud Practitioner Certification 2. At the end of this course you will have all the knowledge and tools to help you identity your strengths and weaknesses in each certification domain areas that are being tested on the certification exam. 7 Steps to Passing the Exam: AWS Certified Solutions Architect Exam Tips 1. You will review sample certification questions in each domain, practice skills with hands-on exercises, test your knowledge with practice question sets, and learn strategies for identifying incorrect responses by interpreting the concepts that are being tested in the exam. The AWS Certified Solutions Architect - Associate examination is intended for individuals who perform a solutions architect role. 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Related: Why Birds of Prey Killed Black Mask So Early In The DCEU McGregor earned considerable praise for his villainous turn, but extra bits of his performance were left on the cutting room floor. However, Harley and Cain form a close bond and the two team up with Detective Renee Montoya (Rosie Perez), Dinah Lance/Black Canary (Jurnee Smollett-Bell), and Helena Bertinelli/The Huntress (Mary Elizabeth Winstead) to take on the Black Mask. In an attempt to spare her life, Harley makes a deal with Roman to retrieve a valuable diamond from the young pickpocket, Cassandra Cain (Ella Jay Basco). In the meantime, check out our 2020 release list to plan your next trip to the movies.Following her break up with the Joker, Harley finds herself to be the target of various criminals of Gotham as she is no longer protected her former flame. Black Mask will be his own challenge, and it sounds like the character will be used to expess misogyny.īirds of Prey will hit theaters on February 7th. The R-rated romp will be heightened and over the top, as Harley's fracture psyche takes us through her story. Overall, it looks like Birds of Prey will bring something totally unique to the DCEU, and the superhero genre as a whole. ![]() J break up early on, which means Margot Robbie's femme fatale is no longer protected from other criminals in Gotham's underworld. While Jared Leto's Joker won't be physically present in Birds of Prey (and the Fantabulous Emancipation of One Harley Quinn), the character will still have a major influence on the movie's plot. She's not getting her power from her partner anymore. Harley is trying to find her freedom-the emancipation of Harley Quinn, right? She's trying to find her voice. But as soon as realizes that Harley's man is out of the picture, she becomes a problem. So that was the only reason he ever put up with her, because was all-powerful. ![]() He's only ever put up with Harley because she was Joker's girlfriend. It plays into the exploration of misogyny in the film. And she's going to be making some gal pals along the way. Unfortunately for him, Margot Robbie's Harley Quinn is an agent of chaos. It looks like Roman Sionis/Black Mask runs his Gotham City empire with an iron fist. Well, that certainly sounds like a conflict waiting to happen. And then Harley comes into this world and she's uncontrollable. But really I feel like we only ever see him in places he controls. We only see him in his club, in his car, in his apartment-or at the end when he's running around. McGregor opened up about what to expect from Black Mask in the highly anticipated blockbuster, saying: The long wait toward the movie's release is almost over, with the cast and crew able to get more chatty about Birds of Prey's contents. Ewan McGregor's involvement in Birds of Prey helped to build its initial buzz, with fans getting a glimpse at the cast in the costume reel that broke the internet during filming. ![]() Even more, it provides guides on the website for getting familiar with the software. For easier navigation, there are sections for every different task you can do. The familiar ribbon-style interface is similar to Microsoft Office. Made with simplicity in mind, even novice users can get the hang of it. ![]() As you can see, the software is rather easy to use and supports Windows, Mac, iOS, and Android systems. Once you upload the file to Google Drive, you need to create a shareable link and send it to the recipient. Google Drive gives you 15GB of free space. Again, the limitation is that both you and the recipient need a Google drive account. Wait a few moments for your file to completely. Last, but not least, you can upload the file to Google Drive. 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You might even have trouble emailing it, depending on which email service you use.Ĭompression is a way to make an existing PDF smaller. For example, if you have a PDF that’s larger than 50MB, you might not be able to upload it to certain websites. Since PDFs can get pretty heavy in size, you might face limitations with sharing them. PDFs, on the other hand, can get quite large, especially if there are many images inside. However, DOC files are usually pretty small when it comes to file size because they pull information from the system on which they are opened, such as installed fonts, for example. Make PDFs smaller to send them via e-mail or upload them to the internet. Use this online PDF kompressor to shrink the file size of your PDF documents. Optimize them for uploading and sending them about the internet by reducing the file volume. In fact, it will also look the same on your smartphone or even your TV. Includes this free virtual PDF compression tool, you can make large PDF files smaller. This means you can create a PDF on a macOS computer and it will look exactly the same on a Windows computer. This makes them very versatile because they look the same across various systems. However, unlike DOC files, PDF files are more like a snapshot of an existing document. It is very similar to the DOC format in that they both contain text, links, and even images. Make a table with two columns labeled x and y corresponding to each interval. ![]() Write the intervals that are shown in the definition of the function along with their definitions.For example, f(x) = ax + b represents a linear function (which gives a line), f(x) = ax 2 + bx + c represents a quadratic function (which gives a parabola), etc, so that we will have an idea of what shape the piece of the function would result in. First, understand what each definition of the function represents.Here are the steps to graph a piecewise function. That has been defined in a piecewise way.We already know that the graph of a piecewise function has multiple pieces where each piece corresponds to its definition over an interval. And so this one actuallyĭoesn't have any jumps in it. So when x is equal to 10, our function is equal to negative six. That is negative 66 over 11, which is equal to negative six. Over 11, is that right? Let's see, if you, yeah, This is going to be, what is this? This is negative 66 I just multiplied this times 10, 12 times 10 is 120, and In that right over there, and then when x is equal to 10, you have negative 120 over 11. Is equal to 66 over 11 which is equal to positive six. It by negative one, plus 54 over 11 which To be positive 12 over 11 'cause we're multiplying When x is negative one, you're going to have, well, this is just going And now let's look at this last interval. So, that's that interval right over there. One, we're approaching negative one plus seven is six. We are approaching, or as x approaches negative Including x equals negative one up to and including, so it's So we're actually able to fill it in, and then when x is negative one, negative one plus seven is Negative two comma five, so it actually includes Two, when x equals negative two negative two plus seven is, The next interval, this one'sĪ lot more straightforward. ![]() I am going to draw my bestĪttempt, my best attempt, at the line. Little open circle there, and then I'm gonna draw the line. We might be tempted, to just circle in this dot over here, but remember, this intervalĭoes not include negative two. Two, we have negative 0.125 times negative two plus 4.75 is equal to, see negative times negative is positive, two times this is going to be point, is going to be positive 0.25 plus 4.75. Includes, so x is defined there, it's less than or equal to, and then we go all the ![]() Negative is a positive, and then 10 times this is That is going to be equal to, let's see, the negative times a Let me do it over here where I do the, so we're going to have negative 0.125 times negative 10 plus 4.75. Negative 10, so we would have negative zero, actually So, when x is equal to 10, sorry, when x is equal to Think about graphing it is let's just plot the endpoints Line, a downward sloping line, and the easiest way I can Less than or equal to x, which is less than negative two, then our function is definedīy negative 0.125x plus 4.75. So, let's think about this first interval. This on your own first before I work through it. If you have some graph paper, to see if you can graph Over this interval for x, this line over this interval of x, and this line over this interval of x. You see this right over here,Įven with all the decimals and the negative signs, It's defined as a different,Įssentially different lines. Have this somewhat hairy function definition here, and I want to see if we can graph it. ![]() Was this article helpful? 0% of 0 players found this article helpful. Resetting your Sim will cancel your Sim's wishes and moodlets, so make sure to check back with your Sims if you need them to complete specific actions. This works for all Sims, not just the ones you are controlling, except in cases of “Sim not found.” Resetting your Sim will return it to a playable state but the Sim will not return to its home lot and its needs will remain the same. Job Description USA Truck is Seeking CDL-A Owner Operators Earn 225,000+/Year - 10,000 Sign-On Bonus - Monthly Safety Performance Bonus Top Pay & Incentives: 10,000 Sign-On Bonus (Paid in 2 Installments of 5,000 at First Dispatch and 5,000 at 90 Days) USA Truck - Owner Operators Leesburg, VA 20 days ago. Select the Reset Object (Debug) option.Press the Shift button and then click on the Sim you want to reset.Type testingcheats true and click Enter.The resetSim * cheat command may not be able to reset all Sims and you may receive a “Sim not found” error. slturbine code- Ctrl + 1 Thrust forward Ctrl + 2 Thrust backwards Ctrl + 3 'Bunny-hop' vehicle Ctrl + 4 Rock car back and forth (can be used to put vehicle on it's wheels again) (Tested on ver. If you need to reset all of the Sims in your current game, you can type resetSim *. Unpause the game, then enter any of the codes while game is paused. For example: If you want to reset Gobias Koffi, type: resetSim Gobias Koffi, and press Enter. But if you really want to stand out, a food truck is one of the cool things to. Now Ive accidentally become the stereotypical truck driver, and Im not sure how I feel. Minecraft Armor Stand Not WorkingStep 2: Move the Items to the Stand. She says that shes only staying with her husband for the kids. Ensure your mic is plugged into the correct port on your sound. 81 Hard Truck 2 Released on By Soft Lab for PC Cheats Screenshots Reviews Forum Hard Truck 2 Cheats Hard Truck 2 cheats, Tips, and Codes for PC. ![]() ![]() I cant move to the U.S., she cant move to Canada either. Sometimes microphone issues are just a small oversight, which can easily happen to anyone. Make sure you enter the name of the Sim you want to reset. My bigger problem is that I am falling in love with my affair partner. Type resetSim Firstname Lastname and click Enter. You may want or need to reset your Sims if they become stuck or unresponsive. There are two ways you can reset your Sim. For either, open the cheat window by pressing CTRL + Shift + C. Hold all these keys at the same time to open the window. Sometimes your Sims get stuck in The Sims 4, but you can reset them with the “resetSim” command in the cheat window. ![]() To download a free Tool Selection Guide, visit. Version: 3.3 License: Free To Try 39. If you go too fast, you risk getting caught and damaging the cable.Ĭlearing grease and ice clogs: The best tool for these stoppages is a water jet, not a drain snake. General purpose NMR processing application, same as iNMR, but can save in PDF only. Guide the cable slowly back and forth to cut through the stoppage thoroughly. Then switch to a larger root cutter like a heavy-duty saw blade, root ripper or ClogChopper. Once the open end of the springs hook onto the object, stop the rotation of your machine and pull the cable out manually so you don't lose your prized catch.Ĭutting tree roots: Even though you'll be tempted to go in with a big root cutter first, it is better to start with a smaller cutter like the spear head or 2-inch U-cutter to get the water flowing first. A retrieving tool (a cone-shaped spring) is designed for just that. ![]() These tools use levers to extend and increase the strength of grip. The shorter part is the jaws and the longer section comprises the handles. INGCO PVC Pipe Cutter, 3-42mm INGCO Heavy Duty Plastic Pipe Cutter,4CR13 Tube Cutter, New Unique Handle Design, One-Hand Fast Pipe Cutting Tool for PVC PPR PE PEX Pipe and Other Plastic Pipe. An average pair has two levers fixed together by a fulcrum, which is located closer to one end. Ideal for Fly Cutting on a Lathe and a Milling. Shank of all 3 pcs in the set are 3/8'. Retrieving loose objects: Sometimes you have to be a hero and recover a lost ring, or get a child's toy or a diaper out of a drain. Cutters are hand tools which are used to cut a variety of materials. Set of 3 Pcs Fly Cutters 3/8' SHANK + HSS Tool Bit Quality Machine tools. You can also adapt any cutter to become a down head by using a down head fitting between the connector and cutter. If you are having problems getting around a tight bend you can switch to a down head boring gimlet or flexible arrow head. Traditional live line systems and tools are constructed using fiberglass-reinforced plastics coated with epoxy. A boring gimlet or an arrow head are good starting tools for small lines. Choose the right tool and you’ll get the line clear the first time.Ĭlearing sinks and tubs: Small-diameter drains require smaller, more flexible cutters to negotiate the tight bends and traps in the line. The basic procedure in a dissolved gas analysis consists of the following: Taking sample from the termination Extracting the gas from the oil Analyzing the gas sample by computer tomography Interpreting findings according to guidelines of the manufacturer. If you don’t choose the right cutting tool as well, you’ll make the job twice as hard and take twice as long to get done. Get Tools articles, news and videos right in your inbox! Sign up now.Ĭhoosing the right drain cleaning machine for the job is only half the battle. |
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